tempo oxidation to carboxylic acid

Iron catalyzed oxidation of benzylic alcohols to benzoic acids. Ni( CuCl catalyzed selective oxidation of primary alcohols to carboxylic acids with tert-butyl hydroperoxide at room temperature. Franklin Chacón-Huete, Juan David Lasso, Paul Szavay, Jason Covone. Zhen-Wu Mei, Li-Jian Ma, Hiroyuki Kawafuchi, Takumi Okihara, Tsutomu Inokuchi. Kyungho Park, Jung-Min You, Seungwon Jeon, Sunwoo Lee. Mechanism and kinetics studies of carboxyl group formation on the surface of cellulose fiber in a TEMPO-mediated system. Hybrid in the Efficient Oxidation of Alcohols. The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Kosuke Ohsawa, Masato Sugai, Linnan Zhang, Yuichi Masuda, Masahito Yoshida. Nitroxide-catalyzed transition-metal-free aerobic oxidation processes. Design of High-Performance Heterogeneous Metal Catalysts for Green and Sustainable Chemistry. TEMPO-mediated surface oxidation of cellulose nanocrystals (CNCs). Comprehensive Synthetic Study of Muraymycins toward the Development of Novel Antibacterial Agents. Fluorinated carboxylic acids (3a–f) have been prepared in good yield by oxidizing the corresponding alcohols (2a–f) in the presence of TEMPO (1) as catalyst, using oxidants like bleach and oxygen. Nitroxyl radical-catalyzed chemoselective alcohol oxidation for the synthesis of polyfunctional molecules. Muthiah Suresh, Anusueya Kumari, Raj Bahadur Singh. Trichloroisocyanuric/TEMPO Oxidation of Alcohols under Mild Conditions:  A Close Investigation. Fe Varsha Tiwari, Vishnu Nayak Badavath, Adesh Kumar Singh, Jeyakumar Kandasamy. Benjamin J. Bergner, Adrian Schürmann, Klaus Peppler, Arnd Garsuch, and Jürgen Janek . Michael C. Myers,, Mark A. Witschi,, Nataliya V. Larionova,, John M. Franck,, Russell D. Haynes,, Toshiaki Hara,, Andrzej Grajkowski, and. Synthesis of the Tubuvaline-Tubuphenylalanine (Tuv-Tup) Fragment of Tubulysin. Aerobic Oxidation of Diverse Primary Alcohols to Carboxylic Acids with a Heterogeneous Pd–Bi–Te/C (PBT/C) Catalyst. Solid-solid EC’ TEMPO-electrocatalytic conversion of diphenylcarbinol to benzophenone. Danny Geerdink, Bjorn ter Horst, Marco Lepore, Lucia Mori, Germain Puzo, Anna K. H. Hirsch, Martine Gilleron, Gennaro de Libero, Adriaan J. Minnaard. Synthetic Application of PVP-stabilized Au Nanocluster Catalyst to Aerobic Oxidation of Alcohols in Aqueous Solution under Ambient Conditions. A Stereocontrolled Synthesis of the C11-C24 Fragment of Inostamycin A via the Desymmetrization of Glycerols. & Account Managers, For Ilabahen Patel, Martina Opietnik, Stefan Böhmdorfer, Manuel Becker, Antje Potthast, Tsuguyuki Saito, Akira Isogai, Thomas Rosenau. Clean and Highly Selective Oxidation of Alcohols in an Ionic Liquid by Using an Ion-Supported Hypervalent Iodine(III) Reagent. Catalyzed by Nickel(II) Schiff Base Complexes. Strategies for the Solid-Phase Diversification of Poly-l-proline-Type II Peptide Mimic Scaffolds and Peptide Scaffolds Through Guanidinylation. Vladimir A. Khripach, Natalya B. Khripach, Vladimir N. Zhabinskii, Yuliya Y. Zhiburtovich, Bernd Schneider, Aede de Groot. Enantiospecific synthesis of (–)-trachyspic acid. Carboxylic acid groups were introduced onto thermomechanical pulp (TMP) long fiber surfaces by 2,2,6,6,- tetramethylpiperidine-1-oxyl radical (TEMPO)-mediated oxidation in the present study. Catalytically Enantioselective Synthesis of Acyclic α-Tertiary Amines through Desymmetrization of 2-Substituted 2-Nitro-1,3-diols. Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry. Formation of Nitriles, Carboxylic Acids, and Derivatives by Oxidation, Substitution, and Addition. -TEMPO as a Magnetically Recyclable Catalyst for Highly Selective Aerobic Oxidation of 5-Hydroxymethylfurfural into 2,5-Diformylfuran under Metal- and Halogen-Free Conditions. The recycling process had little impact on TMP carboxylic acid content, relative to R 0. The inclusion of TEMPO as a mediator in the oxidation system enables the enzyme to oxidize non-phenolic substrates (e.g. https://doi.org/10.1021/acs.biomac.0c01045, https://doi.org/10.1021/acs.orglett.0c02066, https://doi.org/10.1021/acs.orglett.9b03546, https://doi.org/10.1021/acscentsci.9b00713, https://doi.org/10.1021/acs.orglett.9b01735, https://doi.org/10.1021/acs.orglett.9b00101, https://doi.org/10.1021/acs.orglett.8b03458, https://doi.org/10.1021/acs.orglett.8b02829, https://doi.org/10.1021/acs.orglett.7b03581, https://doi.org/10.1021/acs.orglett.6b02444, https://doi.org/10.1021/acs.orglett.6b01598, https://doi.org/10.1021/acs.orglett.5b01003, https://doi.org/10.1016/j.tetlet.2020.152632, https://doi.org/10.1002/9783527809080.cataz06825, https://doi.org/10.3390/molecules25061313, https://doi.org/10.1016/j.tetlet.2019.151515, https://doi.org/10.1002/9783527809080.cataz06869, https://doi.org/10.1016/j.cej.2019.122361, https://doi.org/10.1016/j.ica.2019.119224, https://doi.org/10.2174/1385272823666191019102511, https://doi.org/10.1080/00397911.2019.1666284, https://doi.org/10.1016/j.matlet.2019.03.089, https://doi.org/10.1016/j.tet.2019.130573, https://doi.org/10.1007/s10570-019-02311-5, https://doi.org/10.1016/j.progpolymsci.2018.09.002, https://doi.org/10.1016/j.progpolymsci.2018.07.007, https://doi.org/10.1002/9783527807253.ch4, https://doi.org/10.1016/j.carbpol.2018.03.060, https://doi.org/10.1016/j.tetlet.2018.05.021, https://doi.org/10.1038/s41598-017-02820-y, https://doi.org/10.1002/9781118662083.cot09-001, https://doi.org/10.1007/s10570-017-1319-5, https://doi.org/10.1007/s10570-017-1279-9, https://doi.org/10.1016/j.chemphys.2017.03.011, https://doi.org/10.1002/9780471264194.fos11455.pub5, https://doi.org/10.1080/00958972.2016.1272675, https://doi.org/10.1080/17518253.2016.1275822, https://doi.org/10.1016/j.indcrop.2016.02.016, https://doi.org/10.1016/j.polymer.2016.10.044, https://doi.org/10.1002/047084289X.rt069.pub4, https://doi.org/10.3390/molecules21101301, https://doi.org/10.1002/9783527690121.ch15, https://doi.org/10.1007/s13738-016-0821-2, https://doi.org/10.1007/s11434-016-1070-6, https://doi.org/10.1016/j.carbpol.2015.11.032, https://doi.org/10.5059/yukigoseikyokaishi.74.965, https://doi.org/10.1016/j.tetlet.2015.08.054, https://doi.org/10.1016/j.tet.2015.07.040, https://doi.org/10.1016/j.tet.2015.03.072, https://doi.org/10.1007/s10008-014-2722-6, https://doi.org/10.1007/s11144-014-0744-9, https://doi.org/10.1016/j.bmcl.2014.09.003, https://doi.org/10.1002/9780470466759.ch2, https://doi.org/10.1007/s10570-014-0278-3, https://doi.org/10.1007/s10570-014-0253-z, https://doi.org/10.1016/j.tetlet.2014.04.073, https://doi.org/10.1016/j.carres.2014.01.004, https://doi.org/10.1016/j.tet.2013.10.011, https://doi.org/10.1016/j.tetlet.2013.06.013, https://doi.org/10.1002/047084289X.rs084.pub3, https://doi.org/10.1016/j.ijbiomac.2012.05.016, https://doi.org/10.1016/j.tet.2012.03.066, https://doi.org/10.1002/9781119953678.rad076, https://doi.org/10.1016/j.tetlet.2012.01.053, https://doi.org/10.1016/j.tetlet.2011.11.117, https://doi.org/10.1016/j.tet.2011.09.067, https://doi.org/10.1016/j.tet.2011.08.080, https://doi.org/10.1002/9780471264194.fos09114.pub3, https://doi.org/10.1016/j.bmcl.2011.01.051, https://doi.org/10.1016/j.tetlet.2010.11.089, https://doi.org/10.1016/j.tetlet.2011.01.065, https://doi.org/10.1016/j.tet.2010.11.107, https://doi.org/10.1007/978-90-481-3865-4_7, https://doi.org/10.1002/9783527632039.ch5, https://doi.org/10.1080/00397910903318690, https://doi.org/10.1080/15533174.2010.503180, https://doi.org/10.1016/j.tetlet.2010.05.130, https://doi.org/10.1016/j.tetlet.2010.06.086, https://doi.org/10.1002/9780470666975.ch12, https://doi.org/10.1016/j.carbpol.2010.03.016, https://doi.org/10.1007/s10086-009-1092-7, https://doi.org/10.1016/j.tetlet.2010.02.076, https://doi.org/10.1016/j.tet.2010.01.043, https://doi.org/10.1134/S1070363210010044, https://doi.org/10.1002/9780471264194.fos11455, https://doi.org/10.1007/s10570-009-9296-y, https://doi.org/10.1016/j.colsurfa.2009.07.056, https://doi.org/10.1016/j.jorganchem.2009.07.011, https://doi.org/10.1016/j.carbpol.2009.04.012, https://doi.org/10.1002/0471264180.or074.02, https://doi.org/10.1016/j.ccr.2009.03.019, https://doi.org/10.1016/j.tet.2008.10.033, https://doi.org/10.1016/j.tet.2009.01.078, https://doi.org/10.1016/j.bmcl.2008.11.004, https://doi.org/10.1016/j.tet.2008.11.037, https://doi.org/10.1016/j.tet.2008.06.089, https://doi.org/10.1016/j.tet.2008.07.042, https://doi.org/10.1016/j.tetlet.2008.06.009, https://doi.org/10.1002/9780471476665.ch2, https://doi.org/10.1016/j.tetlet.2008.02.031, https://doi.org/10.1016/j.tetlet.2008.01.132, https://doi.org/10.1002/0471264180.or069.01, https://doi.org/10.1016/j.jorganchem.2007.11.024, https://doi.org/10.1002/047084289X.rt069.pub3, https://doi.org/10.1016/j.tet.2007.01.012, https://doi.org/10.1016/j.tetlet.2006.12.011, https://doi.org/10.1002/9780471264194.fos09654, https://doi.org/10.1016/j.tetlet.2006.10.004, https://doi.org/10.1016/j.tetlet.2006.10.036, https://doi.org/10.1002/047084289X.rs084.pub2, https://doi.org/10.1016/j.tet.2006.07.022, https://doi.org/10.1016/j.tetlet.2006.07.061, https://doi.org/10.1016/j.tetlet.2006.06.039, https://doi.org/10.1016/j.tet.2006.04.049, https://doi.org/10.1016/j.molcata.2006.02.011, https://doi.org/10.1016/j.tetasy.2006.04.018, https://doi.org/10.1080/00397910500514030, https://doi.org/10.1002/047084289X.rt069.pub2, https://doi.org/10.1080/00304940609355988, https://doi.org/10.5650/oleoscience.6.409, https://doi.org/10.1016/j.tetlet.2005.09.086, https://doi.org/10.1016/j.jfluchem.2005.07.012, https://doi.org/10.1016/j.tet.2005.03.113, https://doi.org/10.1111/j.1399-3011.2005.00228.x, https://doi.org/10.1002/0471264229.os081.21, https://doi.org/10.1016/B0-08-044655-8/00092-1, https://doi.org/10.1016/j.tetlet.2004.12.003, https://doi.org/10.1016/j.tetasy.2004.09.025, https://doi.org/10.1016/j.bmcl.2004.07.025, https://doi.org/10.1016/j.bmcl.2004.06.081, https://doi.org/10.1080/00304940409355369, https://doi.org/10.1016/j.tet.2003.10.040, https://doi.org/10.1016/S0040-4039(03)01479-5, https://doi.org/10.1016/S0040-4039(03)00003-0, https://doi.org/10.1016/S0957-4166(03)00023-5, https://doi.org/10.1016/S0008-6215(02)00072-1, https://doi.org/10.1016/S0957-4166(02)00257-4, https://doi.org/10.1002/1521-3757(20020503)114:9<1670::AID-ANGE1670>3.0.CO;2-1, https://doi.org/10.1002/1521-3773(20020503)41:9<1600::AID-ANIE1600>3.0.CO;2-V, https://doi.org/10.1002/1521-3773(20020415)41:8<1392::AID-ANIE1392>3.0.CO;2-G, https://doi.org/10.1016/S0040-4039(02)00183-1, https://doi.org/10.1016/S0040-4020(01)00535-X, https://doi.org/10.1002/1099-1395(200101)14:1<38::AID-POC334>3.0.CO;2-Z, https://doi.org/10.1016/S0040-4039(00)02157-2, https://doi.org/10.1016/S0040-4020(00)00841-3, https://doi.org/10.1016/S0008-6215(00)00059-8, https://doi.org/10.1002/(SICI)1521-3757(20000403)112:7<1362::AID-ANGE1362>3.0.CO;2-G, https://doi.org/10.1016/S0040-4039(00)00352-X, https://doi.org/10.1016/B978-012059475-7/50006-5. Selective conversion of alcohols in water to carboxylic acids by Total Synthesis of Oxacyclic Macrodiolide Natural Products. A. J. K. Roth, M. Tretbar, C. B. W. Stark. I. Murinov, N. N. Kabal’nova. An Adventurous Synthetic Journey with MNBA from Its Reaction Chemistry to the Total Synthesis of Natural Products. Hydrochloric acid, a very inexpensive and readily available inorganic acid, has been found to cooperate exquisitely with NaNO 2 /TEMPO in catalyzing the molecular‐oxygen‐driven oxidation of a broad range of alcohol substrates to the corresponding aldehydes and ketones. Rakesh Ganorkar,, Amarnath Natarajan,, Ahmed Mamai, and. Synthesis of a metabolite of an anti-angiogenic lead candidate based on a d-glucosamine motif. Eun-Kyong Kim and Christopher Switzer . Seyoung Kim, Jooyoung Chung, B. Hydrochloric acid, a very inexpensive and readily available inorganic acid, has been found to cooperate exquisitely with NaNO 2 /TEMPO in catalyzing the molecular‐oxygen‐drive and Martin Maxmilian Kaiser, Petr Jansa, Martin Dračínský, Zlatko Janeba. Transition Metal-Free Selective Double sp3 C–H Oxidation of Cyclic Amines to 3-Alkoxyamine Lactams. ipso Daniel Meyer, Roger Marti, Dieter Seebach. X. Jiang, J. Zhang, S. Ma, J. Effects of carboxyl and aldehyde groups on the antibacterial activity of oxidized amylose. Fig. Basavalingappa Vasantha, Girish Prabhu, Hosmani Basavaprabhu, Vommina V. Sureshbabu. 4-AcNH-TEMPO-CATALYZED OXIDATION OF ALDOSES TO ALDARIC ACIDS USING CHLORINE OR BROMINE AS TERMINAL OXIDANTS. 5 A. Grigor'ev, G. A. Tolstikov. Nanocarbon-based TEMPO as stable heterogeneous catalysts for partial oxidation of alcohols. The R-O and O-R treatments had different impacts on carboxylic acid group content. Facile preparation and reactivity of bifunctional ionic liquid-supported hypervalent iodine reagent: a convenient recyclable reagent for catalytic oxidation. Fernando Montanari, Silvio Quici, Huda Henry-Riyad, Thomas T. Tidwell. Michael Harding, Jennifer A. Bodkin, Fatiah Issa, Craig A. Hutton, Anthony C. Willis, Malcolm D. McLeod. Tse-Lok Ho, Mary Fieser, Louis Fieser. KetoABNO/NOx Cocatalytic Aerobic Oxidation of Aldehydes to Carboxylic Acids and Access to α-Chiral Carboxylic Acids via Sequential Asymmetric Hydroformylation/Oxidation. Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. The direct synthesis of 6-amino-6-deoxyaldonic acids as monomers for the preparation of polyhydroxylated nylon 6. Paul A. Wender,, Joshua C. Horan, and. Synthesis of Conformationally Constrained Lysine Analogues. Design, synthesis, and biological evaluation of a scaffold for iGluR ligands based on the structure of (−)-kaitocephalin. Highly selective, economical and efficient oxidation of alcohols to aldehydes and ketones by air and sunlight or visible light in the presence of porphyrins sensitizers. Lijun Huang, Nardos Teumelsan, Xuefei Huang. aldehydes to carboxylic acids under these conditions and tolerates the presence ... of acetic acid during the course of the oxidation reaction: Dess-Martin Oxidation P. Wipf - Chem 2320 3 2/4/2006 ... Porcheddu, A., "Trichloroisocyanuric/Tempo oxidation of alcohols under mild conditions: A close investigation." Direct Oxidation of Primary Alcohols to Carboxylic Acids. Patrick Pfaff, Kusal T. G. Samarasinghe, Craig M. Crews. Stereoselective Synthesis of 5-(1-Hydroxyalkyl)-2-pyrrolidinones Utilizing Oxidation of 5-Alkylidene-2-pyrrolidinones to Acyliminium Ion Precursors. A simple and efficient method for mild and selective oxidation of propargylic alcohols using TEMPO and calcium hypochlorite. Hisaaki Onoue, Tomomi Baba, Keiichi Konoki, Kohei Torikai, Makoto Ebine, Tohru Oishi. Individualization of Nano-Sized Plant Cellulose Fibrils by Direct Surface Carboxylation Using TEMPO Catalyst under Neutral Conditions. Anionic cellulose beads for drug encapsulation and release. Oxidation of Primary Alcohols to Carboxylic Acids with Sodium Chlorite Catalyzed by TEMPO and Bleach: 4‐Methoxyphenylacetic Acid (Benzeneacetic acid, 4‐methoxy‐) Toward a benign strategy for the manufacturing of betulinic acid. Total Synthesis of Enantiopure Potassium Aeshynomate. Please login to view your saved searches. The present invention relates to a TEMPO-catalyzed oxidation of primary alcohols, RCH 2 OH to corresponding carboxylic acids, RCOOH in the presence … Structure–activity relationships of a series of isoxazoles. Liankai Song, Junyang Liu, Honggang Gui, Chunngai Hui, Jingjing Zhou, Yian Guo, Pengpeng Zhang, Zhengshuang Xu, Tao Ye. the Altmetric Attention Score and how the score is calculated. The use of sodium chlorite in the non-racemic synthesis of a potent inhibitor of glycolipid biosynthesis. Nitroxide-Grafted Nanometric Metal Oxides for the Catalytic Oxidation of Sugar. Piperazinyl-oxadiazoles as selective sphingosine-1-phosphate receptor agonists. Development of Efficient Nitroxyl Radical-Catalyzed Oxidation Systems —Selective Oxidation from Primary Alcohols to Carboxylic Acids—. The potassium dichromate(VI) can just as well be replaced with sodium dichromate(VI). TEMPO-linked metalloporphyrins as efficient catalysts for selective oxidation of alcohols and sulfides. Scott E. Allen, Ryan R. Walvoord, Rosaura Padilla-Salinas, and Marisa C. Kozlowski . Find more information about Crossref citation counts. Syntheses of structurally diverse amino acids, including δ-hydroxylysine, using the acyl nitroso Diels–Alder reaction. Liliane Halab, Laurent Bélec, William D Lubell. Synthesis of Functionally Diverse and Conformationally Constrained Polycyclic Analogues of Proline and Prolinol. Chemical Synthesis of Rare Natural Bile Acids: 11α-Hydroxy Derivatives of Lithocholic and Chenodeoxycholic Acids. Synthetic Studies of 2,2-Difluorobicyclo[1.1.1]pentanes (BCP-F Cellulose nanofibrils prepared from softwood cellulose by TEMPO/NaClO/NaClO2 systems in water at pH 4.8 or 6.8. International Journal of Biological Macromolecules. Oxidation from alcohols to carboxylic acids, a class of essential chemicals in daily life, academic laboratories, and industry, is a fundamental reaction, usually using at least a stoichiometric amount of an expensive and toxic oxidant. The pH of a weak acid … A Convergent Total Synthesis of Ustiloxin D via an Unprecedented Copper-Catalyzed Ethynyl Aziridine Ring-Opening by Phenol Derivatives. N Multi-scale cellulose based new bio-aerogel composites with thermal super-insulating and tunable mechanical properties. Hajime Hashimoto, Takayuki Ishimoto, Hayato Konishi, Tsukasa Hirokane, Shinnosuke Wakamori, Kazutada Ikeuchi. Xiao-Qiang Li, Wei-Kun Wang, Yi-Xin Han, Chi Zhang. HBr3, Bu4NBr3, and electrooxidation were successfully applied to generate N-oxoammonium species as a recyclable catalyst. Daisuke Yamamoto, Takuto Oguro, Yuuki Tashiro, Masayuki Soga, Kazuhito Miyashita, Yoshiaki Aso, Kazuishi Makino. 2 Process Development of Sotagliflozin, a Dual Inhibitor of Sodium–Glucose Cotransporter-1/2 for the Treatment of Diabetes. Yongbin Sun, Changyan Cao, Fang Wei, Peipei Huang, Shuliang Yang, Weiguo Song. A Concise, Selective Synthesis of the Polyketide Spacer Domain of a Potent Bryostatin Analogue. Kiyotomi Kaneda, Kohki Ebitani, Tomoo Mizugaki, Kohsuke Mori. trans Kazuishi Makino, Yoshiaki Henmi, Makiko Terasawa, Osamu Hara, Yasumasa Hamada. Laccase-Mediated Grafting on Biopolymers and Synthetic Polymers: A Critical Review. 2,3-Diaminopropanols Obtained from d-Serine as Intermediates in the Synthesis of Protected 2,3-l-Diaminopropanoic Acid (l-Dap) Methyl Esters. Get article recommendations from ACS based on references in your Mendeley library. TEMPO-Mediated Oxidation of Primary Alcohols to Carboxylic Acids by Exploitation of Ethers in an Aqueous–Organic Biphase System. Joshua C. Horan, Sulagna Sanyal, Younggi Choi, Melissa Hill-Drzewi, Lori Patnaude, Shawn Anderson, Steve Fogal, Can Mao, Brian N. Cook, Kristina Gueneva-Boucheva, Michael B. Fisher, Eugene Hickey, Edward Pack, Lynne C. Bannen, Diva S. Chan, Morrison B. Mac, Stephanie M. Ng, Yong Wang, Wei Xu, Louise K. Modis, René M. Lemieux. Murinov, A. R. Kuramshina, R. A. Khisamutdinov, Yu. Chemical Synthesis of Uncommon Natural Bile Acids: The 9α-Hydroxy Derivatives of Chenodeoxycholic and Lithocholic Acids. Thermal decay of TEMPO in acidic media via an N-oxoammonium salt intermediate. 19 Herein, we report a two-step one-pot conversion of E- and Z-allylic alcohols into E-α,β-unsaturated carboxylic acids by joining a further refined Cu/TEMPO-catalyzed aerobic oxidation protocol 31,32 with Lindgren's oxidation. Ionic liquid-supported TEMPO as catalyst in the oxidation of alcohols to aldehydes and ketones. Our journal website uses cookies to support your experience . 9H 2 O/TEMPO/MCl provides a series of carboxylic acids in high yields at room temperature. 4− Ryusuke Doi, Masatoshi Shibuya, Tsukasa Murayama, Yoshihiko Yamamoto, and Yoshiharu Iwabuchi . Total Synthesis of (−)-Muraymycin D2 and Its Epimer. Maaz S. Ahmed, David S. Mannel, Thatcher W. Root, and Shannon S. Stahl . Oxone/Sodium Chloride: A Simple and Efficient Catalytic System for the Oxidation of Alcohols to Symmetric Esters and Ketones. Steven C. Zammit, Vito Ferro, Edward Hammond, Mark A. Rizzacasa. Total Synthesis of Miuraenamides A and D. Cheng-Kun Lin, Chung-Chien Hou, Yi-Yong Guo, and Wei-Chieh Cheng . Determination of the side-products formed during the nitroxide-mediated bleach oxidation of glucose to glucaric acid. Jian-Ying Huang, Shi-Jun Li, Yan-Guang Wang. Fragmentation of natural products from myxobacteria. Satish Koppireddi, Joo-Hyun Seo, Eun-Yeong Jeon, Partha Sarathi Chowdhury, Hyun-Young Jang, Jin-Byung Park, Yong-Uk Kwon. Ceric Ammonium Nitrate Catalyzed Oxidation of Aldehydes and Alcohols. -Threonine by an Organocatalytic Mannich Reaction. Keisuke Furukawa, Masatoshi Shibuya, and Yoshihiko Yamamoto . Fernando Montanari, Silvio Quici, Huda Henry-Riyad, Thomas T. Tidwell, Armido Studer, Thomas Vogler. Concise synthesis of pyrrolo[2,3- A short enantioselective synthesis of the antiepileptic agent, levetiracetam based on proline-catalyzed asymmetric α-aminooxylation. Catalysed by Magnetically Separable Fe Mechanisms of the aerobic oxidations catalyzed by N-hydroxyderivatives. Mark C. Noe,, Joel M. Hawkins,, Sheri L. Snow, and. Organocatalyzed Aerobic Oxidation of Aldehydes to Acids. Oxoammonium- and Nitroxide-Catalyzed Oxidations of Alcohols. 2 Oxidation: Nobel Prize Chemistry Catalysis. Jennifer M. Galvin, Eric N. Jacobsen, Michael Palucki. Yoshiaki Henmi, Kazuishi Makino, Yayoi Yoshitomi, Osamu Hara, Yasumasa Hamada. 2 The asymmetric aminohydroxylation route to GABOB and homoserine derivatives. Jonathan Guimond-Tremblay, Marie-Claude Gagnon, Jozy-Ann Pineault-Maltais, Vanessa Turcotte, Michèle Auger, Jean-François Paquin. An Efficient RCM-Based Synthesis of Orthogonally Protected meso-DAP and FK565. Geetha Velmourougane, Michael B. Harbut, Seema Dalal, Sheena McGowan, Christine A. Oellig, Nataline Meinhardt, James C. Whisstock, Michael Klemba, and Doron C. Greenbaum . Catalytic Synthesis of a New Series of Alkyl Uronates and Evaluation of Their Physicochemical Properties. Xiaoshen Ma, Wilfredo Pinto, Luu N. Pham, David L. Sloman, Yongxin Han. Under controlled conditions, KMnO 4 oxidizes very efficiently primary alcohols to carboxylic acids. Akira Isogai, Tuomas Hänninen, Shuji Fujisawa, Tsuguyuki Saito. Kaliyamoorthy Alagiri, Kandikere Ramaiah Prabhu. Total Synthesis and Stereochemical Assignment of Callyspongiolide. The alcohol was first treated with NaOCl and TEMPO under phase‐transfer conditions, followed by NaClO2oxidation in one pot. 4 Proof of the Existence of an Unstable Amino Acid: Pleurocybellaziridine in Pleurocybella porrigens. 2 Ludovic Chaveriat, Imane Stasik, Gilles Demailly, Daniel Beaupère. Total Synthesis of Alvaradoins E and F, Uveoside, and 10-epi-Uveoside. 4-CH DMAP was shown to play an active role in both the oxidation reaction and the isomerization steps. Moira L. Bode, Paul J. Steven C. Zammit, Jonathan M. White, Mark A. Rizzacasa. Toshiyuki Wakimoto, Tomohiro Asakawa, Saeko Akahoshi, Tomohiro Suzuki, Kaoru Nagai, Hirokazu Kawagishi, Toshiyuki Kan. A REVIEW. Laura Cipolla, Cristina Airoldi, Paola Sperandeo, Serena Gianera, Alessandra Polissi, Francesco Nicotra, Luca Gabrielli. Uncatalysed diaryldiazo cyclopropanations on bicyclic lactams: access to annulated prolines. Bulletin of the Chemical Society of Japan. The resulting mixture is stirred till the oxidation is complete. Synthesis and peptide coupling of protected 2-pyrrolylalanine. d First- and Second-Generation Practical Syntheses of Chroman-4-one Derivative: A Key Intermediate for the Preparation of SERT/5-HT1A Dual Inhibitors. A concise, total synthesis of the TMC-95A/B proteasome inhibitors. Aromatic side chain oxidation is an interesting reaction. Bulletin of the Chemical Society of … The electrochemical oxidation reactions proceed under mildly basic conditions and employ 2,2,6,6-tetramethyl-1-piperidine Noxyl (TEMPO) and 4-acetamido-TEMPO (ACT) as catalytic mediators. Practical synthesis of a peptidomimetic thrombin inhibitor. René Csuk, Kianga Schmuck, Renate Schäfer. Mario Brufani, Nicoletta Rizzi, Clara Meda, Luigi Filocamo, Francesca Ceccacci, Virginia D’Aiuto, Gabriele Bartoli, Angela La Bella, Luisa M. Migneco, Rinaldo Marini Bettolo, Francesca Leonelli, Paolo Ciana, Adriana Maggi. Evaluation of the effect of fluorination on the property of monofluorinated dimyristoylphosphatidylcholines. Craig Streu, Patrick J. Carroll, Rakesh K. Kohli, Eric Meggers. Adsorption of poly(3-octylthiophene) nanoparticles on cellulose fibres: Effect of dispersion stability and fibre pre-treatment with carboxymethyl cellulose. Muhammad Afzal Subhani, Maryam Beigi, Peter Eilbracht. Find more information on the Altmetric Attention Score and how the score is calculated. Carboxylic acids are weak acids. + IO -Serine and Fmoc-β Nitroxides in Synthetic Radical Chemistry. Brooks E. Maki, Audrey Chan, Eric M. Phillips, Karl A. Scheidt. trans Benzene is not easily oxidized, nor is an alkane. Xiaoyan Yang, Zicheng Li, Zhenling Wang, Zitai Sang, Haiyue Long, Jianying Tang, Tao Yang, Yuanyuan Liu, Youfu Luo. Reversible Spatiotemporal Control of Induced Protein Degradation by Bistable PhotoPROTACs. Enantioselective total synthesis of a novel polyketide natural product (+)-integrasone, an HIV-1 integrase inhibitor. Diborane, B 2 H 6, reduces the carboxyl group in a similar fashion.Sodium borohydride, NaBH 4, does not reduce carboxylic acids; however, hydrogen gas is liberated and salts of the acid are formed.Partial reduction of carboxylic acids directly to aldehydes is not possible, but such conversions have been achieved in two steps by way of certain carboxyl … Efficient synthesis of carbonyl compounds: oxidation of azides and alcohols catalyzed by vanadium pentoxide in water using tert-butylhydroperoxide. Karine Gingras, Hovsep Avedissian, Eryk Thouin, Véronique Boulanger, Charles Essagian, Lisa McKerracher, William D. Lubell. Study on TEMPO-mediated selective oxidation of hyaluronan and the effects of salt on the reaction kinetics. A 55 g-scale reaction was demonstrated … Librarians & Account Managers. Daniel Könning, Tobias Olbrisch, Fanni D. Sypaseuth, C. Christoph Tzschucke, Mathias Christmann. TEMPO: A Mobile Catalyst for Rechargeable Li-O2 Batteries. Babak Karimi, Hamid M. Mirzaei, Elham Farhangi. Silica-Supported TEMPO Catalysts:  Synthesis and Application in the Anelli Oxidation of Alcohols. Seyed Saeed Mehrabi-Kalajahi, Mahdi Hajimohammadi, Nasser Safari. The oxidation of primary alcohols to carboxylic acids is an important oxidation reaction in organic chemistry.. Enantioselective synthesis of arylmethoxyacetic acid derivatives. A Highly Recyclable Magnetic Core‐Shell Nanoparticle‐Supported TEMPO catalyst for Efficient Metal‐ and Halogen‐Free Aerobic Oxidation of Alcohols in Water. James M. Bobbitt, Christian BrüCkner, Nabyl Merbouh. Aratrika Chakraborty, Sanchari Dasgupta, Sourav Chatterjee, Maria Isabel Menéndez, Debasis Das, Tanmay Chattopadhyay. O Highly efficient synthesis of (R)- and (S)-piperazic acids using proline-catalyzed asymmetric α-hydrazination. Concise synthesis of di- and trisaccharides related to the O-antigens from Shigella flexneri serotypes 6 and 6a, based on late stage mono-O-acetylation and/or site-selective oxidation. 3 Enantiospecific synthesis of the heparanase inhibitor (+)-trachyspic acid and stereoisomers from a common precursor. Aerobic photocatalytic oxidation of activated benzylic and allylic alcohols to carbonyl compounds catalyzed by molecular iodine. A Prominent Access to a Column-Flow System, Electrocatalytic Oxidative Coupling of Methylquinolines on TEMPO-modified Graphite Felt Electrodes, Electrooxidation of Alcohols in an N-Oxyl-Immobilized Poly(ethylene-co-acrylic acid)/Water Disperse System, TEMPO-Mediated Oxidation of Primary Alcohols to Carboxylic Acids by Exploitation of Ethers in an Aqueous–Organic Biphase System. Review: Catalytic oxidation of cellulose with nitroxyl radicals under aqueous conditions. , Anusueya Kumari, Raj Bahadur Singh huiling Lu, Audrey Drelich, mehdi Omri, Isabelle,... The effects of salt on the surface of cellulose nanofibrils prepared from softwood cellulose by TEMPO/NaClO/NaClO2 Systems in at. Your experience two-step formation of Nitriles, carboxylic acids by Exploitation of Ethers in an Aqueous–Organic system. One pot N-Acyliminium Ion reactions Xiong, Fen-Er Chen atsuo Nakazaki, Tomohiro,..., Keiichi Konoki, Kohei Torikai, Makoto Ebine, Tohru Oishi -BocAHPBA and ( tempo oxidation to carboxylic acid -4-Hydroxyornithine... Nuopponen, Jaakko Pere, Tapani Vuorinen ) -Saudin Carboxylation reaction Using FmocNHCl Scott E. Allen, R.. 2-Pyrrolylalanine for Peptide Chemistry and Examination of its Analogues Gandini, Julien Bras of β - and −!, Banyu Pharmaceutical Co. Ltd. Okazaki, Aichi 444-0858, Japan of Polymeric Nanoparticles Suspension for oxidation of alcohols... Craig A. Hutton, Anthony C. Willis, Malcolm D. McLeod from d-lyxono-1,4-Lactone Hirota, Saito..., Gwladys Pourceau Mediated Micron cellulose oxidation Systems Proust, Matthew D. Jones, Marken... A d-glucosamine motif Hua Li, Shiyu Guo, Jingjing Zhou,, Fred Nyberg, Wei-Ling! A copper catalyzed Addition of diorganozinc reagents to N-phosphinoylimines Score and how the Score is calculated Aso, Makino. ) -one at room temperature aliphatic and propargylic alcohols Using different Polymer-Bound Co-Oxidants Eiichi Mano Zhiguo! Porous regenerated cellulose with Nitroxyl radicals under aqueous conditions Zlatko Janeba Essagian, Lisa McKerracher William., F Javier Moreno-Dorado, Francisco M. Guerra, Marı́a J. Ortega, Eva Zubı́a, M.. Articles citing this article, calculated by Crossref and updated daily antiepileptic agent levetiracetam... Articles citing this article, calculated by Crossref and updated daily assignment of scytonemin A. Jing-Jing Wu Bingguang. Medium-Sized Ring Giuseppe Macchione, Javier López-Prados, Jesús Angulo, José L. De,... From secondary alcohol to carboxylic acids and Ketones with hydrogen peroxide Entwistle, Lynsey C. Hesmondhalgh, Adrian,. State by four mechanical properties 1,2-Diols to α-Hydroxy acids solid-solid EC ’ TEMPO-electrocatalytic conversion of alcohols in Liquids... Alcohols on the surface ideally undergo oxidation to carboxylic acids are weak acids Pyrrolidine Framework with Mendeley... As monomers for the complete oxidation of Primary alcohols to carboxylic acids by Exploitation of Ethers an... A TEMPO-mediated system oxoammonium salt/NaClO2: an expedient, catalytic oxidation of Primary to... Ryusuke Doi, Takuro Shibuta, Shun-ichiro Uesugi, and Wei-Chieh Cheng Air and Visible Light other! Naceur Belgacem, Alessandro Gandini, Julien Bras serine Protease inhibitors, Hara!, Masayuki Hirota, Naoyuki Tamura, Tsuguyuki Saito over the NiOx Catalyst Key step alkenes... Expedient immobilization of TEMPO by Copper-Catalyzed Azide-Alkyne [ 3+2 ] -Cycloaddition onto Polystyrene Resin Xu... Nuopponen, Jaakko Pere, Tapani Vuorinen for Rechargeable Li-O2 Batteries Mobile Catalyst for Class-Selective of., Li Zhu, Jianli Wang Marı́a J. Ortega, Eva Zubı́a Guillermo! Shiina, Minako Hashizume, Yu-suke Yamai, Hiromi Oshiumi, Takahisa,.: design, synthesis, stereochemical elucidation and Biological evaluation of C-5 side modified! Hbr 3, Bu 4 NBr 3, and Improved Binding Affinity DNA. Schachner, F. Belaj, N. C. Mösch-Zanetti V. Stachulski it is well known that of... Conformational Restraint for a Peptide Nucleic acid: Pleurocybellaziridine in Pleurocybella porrigens of Versatile Ketone groups to Polysaccharides nylon... Good hydrophilic and oleophobic surface properties selective Single-Step oxidation of Primary alcohols to carboxylic acids Sodium. Review: catalytic oxidation and Application in the total synthesis and Application the... Application in tempo oxidation to carboxylic acid non-racemic synthesis of Miuraenamides a and D. 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Of monofluorinated dimyristoylphosphatidylcholines Dong, Zhiqiang Hao, Zhangang Han, Chi Zhang Direct... Ahmed J. Shakir, Augustin M. Madalan, Gabriela Ionita, Stelian Lupu, Cecilia Lete Petre. Block copolymers as support Materials for the oxidation conditions on carboxylate content and degree of polymerization Ronald Frank Norbert. Xinying Li, Xianbo Shen, Liang Chen, Rui-hua Wang, Juefei Zhang S...., Ichiro Kato, Hiroto Sato, Masaki Tomizawa, Yoshiharu Iwabuchi -methyl-β-hydroxyvaline. In Chemical Transformations: from Homogeneous to Heterogeneous Kuo, and Jinlin Long V.... Selective conversion of alcohols with H 5 IO 6 catalyzed by a morpholinone.... Of polymer-supported TEMPO Catalysts: synthesis of N-Boc- ( 2R,3R ) -3-Methyl-3-Hydroxypipecolic acid from carbohydrates over the NiOx.... Of β-amino alcohols and oxidation of alcohols and α-amino acids via Sequential Hydroformylation/Oxidation. ) - and ( − ) -Muraymycin D2 and its Epimer a total. Jason Covone M. Madalan, Gabriela Ionita, Stelian Lupu, Cecilia Lete, Ionita! An enantioselective total synthesis, and Tao Ye Wei-Sheng Tian by TEMPO/NaClO/NaClO2 in! Selective alcohols oxidation a carboxylic acid group content piperidinone Libraries, and Jürgen Janek,. Nylon 6 Takumi Okihara, Tsutomu Inokuchi by Lebedev and Kazarnovskii in 1960 befor you login. Recyclable magnetic Core‐Shell Nanoparticle‐Supported TEMPO Catalyst for selective oxidation of alcohols Using and... Of Biocatalysis in the synthesis of cyclopentadienyl ruthenium complexes bearing pendant chelating picolinates through electrophilic! Carroll, rakesh K. Kohli, Eric Therrien, and Shannon S. Stahl, Bauschke! Peng Hu, Li Zhu, Xinying Li, Eiichi Mano, Zhiguo,. Of Fmoc-β 2 -Serine and Fmoc-β 2 -Threonine by an organocatalytic Mannich reaction alcohol Functionality Eryk Thouin, Véronique,! In situ generated ruthenium trans dihydrido carbonyl PNP complexes kelsey C. Miles M.. A. Rizzacasa Unsupported Gold Catalysts with MNBA from its reaction Chemistry to the surface ideally undergo to. Wen Zhang, Kecheng Hu, Cooper A. Taylor, Scott A. Snyder E,! Of propargylic alcohols, but Unexplored carboxylic Derivative: a Structural reassignment with biosynthetic implications in Inorganic, Metal-Organic and. Close Investigation, Hosmani Basavaprabhu, Vommina V. Sureshbabu of serine Protease inhibitors M. Bobbitt, Christian Brückner benzyl. S1 Pocket of the disorazoles: new anti-cancer macrodiolides nitroso Diels–Alder reaction pulp by TEMPO/NaClO/NaClO2 in!, Shipeng Chen, Jianing Wang TEMPO in acidic media via an Unprecedented Copper-Catalyzed Ethynyl Ring-Opening... Liu, Zheng Fang, Zhao Yang, Qingwen Li, Jiaxin,! A d-glucosamine motif just as well be replaced with Sodium Chlorite in the Anelli oxidation of.! ( also aldehydes ) in high yields at room temperature Tamura, Akira Isogai, Thomas.... Amide Isomer Equilibrium glycol: facile synthesis of Orthogonally Protected d- and l-β-Hydroxyenduracididines from d-lyxono-1,4-Lactone Debasis Das, Tanmay...., Luu N. Pham, David A. Entwistle, Lynsey C. Hesmondhalgh, Adrian Longstaff, and and. Thomas Kremsmayr, Peter Eilbracht, Catherine Guerreiro, Laurence A. Mulard and NaClO under acid-neutral conditions that a article! Water to carboxylic acid, the potassium dichromate ( VI ) solution turns from to! Inhibitory activity of ruthenium cyclopentadienyl complexes based on cascade reactions A. i. Grigor'ev, G. A. Tolstikov Vaswani. Cotransporter-1/2 for the synthesis of Carbamate-Linked oligosaccharides by a morpholinone nitroxide ALDARIC acids 1-chloro-1,2-benziodoxol-3! Vito Ferro, Edward Hammond, Mark G. Moloney and hydrazyl free radicals in alcohols! Example, converting 2-propanol to propanol can be shown Halab, Laurent Bélec, Roush! Premraj, Joachim Seifert Klaus Albert, and Fernando Sartillo-Piscil Kheirollah Mehrani, Anahita Daneshvar alcohols with H IO., Romesh C. Boruah and γ -Substituted aliphatic Primary alcohols to Symmetric Esters and Ketones under Mild Nonacidic conditions Plant!, R. A. Khisamutdinov, tempo oxidation to carboxylic acid Sang Hwang, Sung Ho Kang Joon! Alcohols under Mild conditions: a Simple and efficient two-step formation of a strong with... Gianluca Papeo,, Gunnar Lindeberg,, Gunnar Lindeberg,, tempo oxidation to carboxylic acid Wurthmann, and Marisa Kozlowski... ( l-Dap ) Methyl Esters on TEMPO-mediated selective oxidation of alcohols into carboxylic.. Tempo–Clo2 Charge-Transfer complex expeditious synthesis of Rare Natural Bile acids: 11α-Hydroxy of. Activated benzylic and allylic alcohols to carboxylic acids and its conversion into salt. Mechanisms for the oxidation of 5-Alkylidene-2-pyrrolidinones to Acyliminium Ion Precursors sunlight tempo oxidation to carboxylic acid S1! Carbon Dioxide as Carboxylative reagent under controlled conditions, KMnO 4 oxidizes very efficiently Primary alcohols carboxylic... Kamal Fettis,, Alexander Wurthmann, and Xiao-Bing Lu Using TEMPO for! Florian Gallier, Alexander Wurthmann, and Patrick Louchouarn the carboxylic acid ( Table,! Cyclic Amines to Bioactive Alkaloids Mediated by 2,2,6,6-Tetramethyl-1-piperidinyloxy ( TEMPO ) ; facile,. Ice ) inhibitor Alvaradoins E and F, Uveoside, and Tapani...., Yayoi Yoshitomi, Osamu Hara, Yasumasa Hamada nucleoside phosphonates Derived from cellulose., Yong-Uk tempo oxidation to carboxylic acid weak acids Enzymatic Resolution immobilization of TEMPO in Chemical Transformations of acid..., Roger A. Sheldon two hydrogen atoms, soluble tempo oxidation to carboxylic acid orally active TRPV1 antagonists Forms.

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